Since chlorine's outermost orbital is a 3p orbital, there is more space, and the electrons in this orbital are inclined to share this space with an extra electron. Therefore, chlorine has a higher electron affinity than fluorine, and this orbital structure causes it to have the highest electron affinity of all of the elements. Hypochlorite is an ion composed of chlorine and oxygen with the chemical formula ClO−. Being unstable in the pure form, hypochlorite is most commonly used for bleaching, disinfectation, and water treatment purposes in its salt form, sodium hypochlorite.Hypochlorite is often used as a chemical reagent for chlorination and oxidation reactions. Chlorine and oxygen are located at 7 and 6 groups respectively in the periodic table. So chlorine has seven electrons in its valence shell. In oxygen atom, there are six electrons in its valence shell. Total valence electrons given by chlorine atoms = 7.1 = 7; There are three oxygen atoms in ClO 3-, Therefore. Chlorine has the electron configuration Ne3s 2 3p 5, with the seven electrons in the third and outermost shell acting as its valence electrons. Like all halogens, it is thus one electron short of a full octet, and is hence a strong oxidising agent, reacting with many elements in order to complete its outer shell.
Chlorine Atom vs Chloride Ion
In writing the electron configuration for Chlorine the first two electrons will go in the 1s orbital. Since 1s can only hold two electrons the next 2 electrons for Chlorine go in the 2s orbital. The next six electrons will go in the 2p orbital. The p orbital can hold up to six electrons.
The elements in the periodic table are not stable except the noble gases. Therefore, elements try to react with other elements, to gain the noble gas electron configuration to achieve stability. Likewise, chlorine also has to get an electron to achieve the electron configuration of the noble gas, Argon. All metals react with chlorine, forming chlorides. Except some similarities, Chlorine and chloride has different physical and chemical properties due to the change of one electron.
Chlorine Atom
Chlorine is an element in the periodic table which is denoted by Cl. It is a halogen (17th group) in the 3rd period of the periodic table. The atomic number of chlorine is 17; thus, it has seventeen protons and seventeen electrons. Its electron configuration is written as 1s2 2s2 2p6 3s2 3p5. Since the p sub level should have 6 electrons to obtain the Argon noble gas electron configuration, chlorine has the ability to attract an electron. Chlorine has a very high electro negativity, which is about 3, according to the Pauling scale. The atomic weight of chlorine is 35.453 amu. Under room temperature, chlorine exists as a diatomic molecule (Cl2). Cl2 is a yellow – greenish color gas. Chlorine has a melting point of -101.5 °C and a boiling point of -34.04 °C. Among all the chlorine isotopes, Cl-35 and Cl-37 are the most stable isotopes. In the atmosphere, 35Cl present in 75.77% and 37Cl present in 24.23%. When chlorine gas is dissolved in water, it forms hydrochloric acid and hypochlorous acid, which are highly acidic. Chlorine has all the oxidation numbers varying from -1 to +7.
Chloride Ion
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Chlorine Electrons And Protons
Chloride is the resulted anion when chlorine abstracts an electron from another electropositive element. Chloride is represented by the symbol Cl–. Chloride is a monovalent ion with -1 charge. Therefore, it has 18 electrons and seventeen protons. The electron configuration of chloride is 1s2 2s2 2p6 3s2 3p6. Chloride exists in ionic compounds such as sodium chloride, calcium chloride and HCl, which are ionic. Chloride also exists naturally in water sources, and this is the most common anion in the nature. There is a considerable amount of chloride ions in sea water. Chloride ions can participate in conducting electricity through solvents.
Chlorine Valence Electrons
What is the difference between Chlorine Atom and Chloride Ion? • Chloride ion is the reduced form of chlorine atom. Chloride has 18 electrons compared to seventeen electrons of chlorine, and both have seventeen protons. Therefore, chloride has a negative (-1) charge whereas chlorine is neutral. • Since there is an additional electron in the chloride ion than the atom, the ionic radius differs from the atomic radius of chlorine. With additional electron in the outer shell, chloride ion tends to expand due to the electron repulsion between each other. This causes an increase in ionic radius for chloride than the chlorine atomic radius. • Chlorine is more chemically reactive than chloride because it is more unstable. • Chloride has achieved the Argon electron configuration, therefore, stable than the chlorine atom. • Chloride ion is attracted to positively charged electrodes or other positively charged chemical species, but chlorine does not. |